色谱

色谱 ›› 2010, Vol. 28 ›› Issue (11): 1103-1106.DOI: 10.3724/SP.J.1123.2010.01103

• 技术与应用 • 上一篇    下一篇

气相色谱法分析甘蓝及其土壤中的烯啶虫胺残留

张贵群1, 聂思桥2, 龙丽萍1, 曾东强1, 陈九星2*, 杨辉3, 陈玲珑4   

  1. 1. 广西大学农学院, 广西 南宁 530004; 2. 湖南化工研究院国家农药创制工程技术研究中心, 湖南 长沙 410007; 3. 中南大学化学化工学院, 湖南 长沙 410083; 4. 湖南师范大学化学化工学院, 湖南 长沙 410081
  • 收稿日期:2010-08-13 修回日期:2010-09-21 出版日期:2010-11-28 发布日期:2010-11-28
  • 通讯作者: 陈九星,研究员,从事农药残留分析.
  • 基金资助:

    农业部农药残留试验项目(编号: 2009P469).

Determination of nitenpyram residue in cabbage and soil using gas chromatography

ZHANG Guiqun1, NIE Siqiao2, LONG Liping1, ZENG Dongqiang1, CHEN Jiuxing2*, YANG Hui3, CHEN Linglong4   

  1. 1. College of Agriculture, Guangxi University, Nanning 530004, China; 2. National Engineering Research Center for Agrochemicals, Hunan Research Institute of Chemical Industry, Changsha 410007, China; 3. College of Chemistry and Chemical Engineering of Central South University, Changsha 410083, China; 4. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China
  • Received:2010-08-13 Revised:2010-09-21 Online:2010-11-28 Published:2010-11-28

PDF

708

被引次数

50

摘要： 建立了气相色谱测定甘蓝植株和土壤中烯啶虫胺残留量的分析方法。样品采用丙酮-水(4:1, v/v)进行提取,经弗罗里硅土柱净化,用电子捕获检测器进行测定。实验结果表明,添加水平为0.02～2.00 mg/kg时,烯啶虫胺在甘蓝植株和土壤中的平均回收率分别为88.73%～94.13%和90.82%～96.27%,相对标准偏差分别为3.09%～7.39%和2.01%～4.92%;方法的最低检出限为0.02 mg/kg。该方法快速简便、灵敏度高、重现性好,可用于环境系统中烯啶虫胺残留量的检测分析。

关键词: 甘蓝, 气相色谱, 土壤, 烯啶虫胺

Abstract: An analytical method for the determination of nitenpyram residue in cabbage and soil using gas chromatography was established. The nitenpyram residue was extracted from cabbage and soil with acetone-water (4:1, v/v), cleaned up by a Florisil column, and then detected by gas chromatography-electron capture detection (GC-ECD). At the spiked level range from 0.02 to 2.00 mg/kg, the average recoveries of nitenpyram were 88.73%~94.13% and 90.82%~96.27% with the relative standard deviations (RSDs) of 3.09%~7.39% and 2.01%~4.92%in cabbage and soil, respectively. The limit of detection of nitenpyram was 0.02 mg/kg. The method is fast, sensitive, simple, reproducible and practical for the determination of nitenpyram residue in environmental systems.

Key words: cabbage, nitenpyram, soil, gas chromatography (GC)