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Extraction chromatographic separation of platinum(IV) from real samples and associated elements

KOKATE Sudarshan Jagdish, KUCHEKAR Shashikant Raghunath*   

  1. P. G. Department of Analytical Chemistry Padmashri Vikhe Patil College, Pravaranagar,At/Po.-Loni (Kd), Tal. Rahata, Dist. Ahmednagar 413713, MS, India
  • 收稿日期:2009-03-16 修回日期:2009-05-16 出版日期:2009-11-30 发布日期:1981-12-25
  • 通讯作者: KUCHEKAR Shashikant Raghunath

Extraction chromatographic separation of platinum(IV) from real samples and associated elements

KOKATE Sudarshan Jagdish, KUCHEKAR Shashikant Raghunath*   

  1. P. G. Department of Analytical Chemistry Padmashri Vikhe Patil College, Pravaranagar,At/Po.-Loni (Kd), Tal. Rahata, Dist. Ahmednagar 413713, MS, India
  • Received:2009-03-16 Revised:2009-05-16 Online:2009-11-30 Published:1981-12-25
  • Contact: KUCHEKAR Shashikant Raghunath

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摘要： The extraction behavior of platinum(IV) was studied with N-n-octylaniline as a function of different parameters, such as pH, concentrations of weak acids, mineral acids, reagents and elution time. A selective method was developed for the extraction chromatographic studies of platinum(IV) and its separation from several metal ions with N-n-octylaniline (liquid anion exchanger) as a stationary phase on silica gel. The quantitative extraction of platinum(IV) was observed with 0.067 mol/L N-n-octylaniline and 0.015 mol/L ascorbic acid at pH 1.0. Metal ion was stripped from the column with water and determined spectrophotometrically with stannous chloride method. The proposed method is free from the interference of a large number of cations and anions. Platinum(IV) was separated from pharmaceutical preparations, alloys and synthetic mixtures. Mutual separation scheme was developed for platinum(IV), palladium(II) and gold(III). The log-log plot of N-n-octylaniline concentration versus the distribution ratio indicates that the probable extracted species is ［RR′NH+2 ］· Pt(C6H7O6)－3.

关键词: gold(III) , mutual separations, palladium(II), platinum(IV), extraction chromatography

Abstract: The extraction behavior of platinum(IV) was studied with N-n-octylaniline as a function of different parameters, such as pH, concentrations of weak acids, mineral acids, reagents and elution time. A selective method was developed for the extraction chromatographic studies of platinum(IV) and its separation from several metal ions with N-n-octylaniline (liquid anion exchanger) as a stationary phase on silica gel. The quantitative extraction of platinum(IV) was observed with 0.067 mol/L N-n-octylaniline and 0.015 mol/L ascorbic acid at pH 1.0. Metal ion was stripped from the column with water and determined spectrophotometrically with stannous chloride method. The proposed method is free from the interference of a large number of cations and anions. Platinum(IV) was separated from pharmaceutical preparations, alloys and synthetic mixtures. Mutual separation scheme was developed for platinum(IV), palladium(II) and gold(III). The log-log plot of N-n-octylaniline concentration versus the distribution ratio indicates that the probable extracted species is ［RR′NH+2 ］· Pt(C6H7O6)－3.

Key words: gold(III) , mutual separations, palladium(II), platinum(IV), extraction chromatography