色谱

色谱

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气相色谱-氮化学发光检测法分析催化汽油中含氮化合物类型的分布

杨永坛*, 吴明清, 王征   

  1. 中国石油化工股份有限公司石油化工科学研究院, 北京 100083
  • 收稿日期:2009-10-15 修回日期:2009-12-15 出版日期:2010-04-28 发布日期:1980-12-25
  • 通讯作者: 杨永坛

Determination of nitrogen compounds in catalytic gasolines by gas chromatography-nitrogen chemiluminescence detection

YANG Yongtan*, WU Mingqing, WANG Zheng   

  1. Research Institute of Petroleum Processing, China Petroleum & Chemical Corporation, Beijing 100083, China
  • Received:2009-10-15 Revised:2009-12-15 Online:2010-04-28 Published:1980-12-25
  • Contact: YANG Yongtan

PDF

746

被引次数

15

摘要： 建立了催化汽油馏分中各种含氮化合物类型分布的气相色谱-氮化学发光检测分析方法,考察了各种色谱条件对含氮化合物分离的影响。采用化学预处理的方法浓缩了催化汽油中的含氮化合物,并结合气相色谱-质谱检测以及部分含氮化合物标准样品,对某催化汽油中的20多个含氮化合物进行了定性(或归类)。催化汽油中几种主要含氮化合物(苯胺、2-甲基苯胺、二甲基苯胺)含量测定值的相对标准偏差(RSD)均不大于2.5%。当信噪比(S/N)为3时,苯胺氮的检出限为1.0 mg/L。该方法可用于不同来源和不同加工工艺的汽油馏分中各种含氮化合物类型分布的研究。

关键词: 催化汽油 , 分布, 含氮化合物, 气相色谱-氮化学发光检测, 气相色谱-质谱

Abstract: A method for the separation and determination of nitrogen compounds in catalytic gasolines by gas chromatography-nitrogen chemiluminescence detection (GC-NCD) was established. The effects of the flow rate of carrier gas and the oven temperature on the resolution were studied. More than 20 nitrogen compounds, including amines, pyridine, aniline, 2-methyl aniline, 3-methyl aniline, 4-methyl aniline, quinoline, and indole, in catalytic gasoline were identified based on the retention time of some pure nitrogen compounds and by gas chromatography-mass spectrometry. The relative standard deviations of the peak areas of main nitrogen compounds in a catalytic gasoline sample were less than 2.5% and the detection limits for nitrogen were 1.0 mg/L under the chosen conditions. The linear ranges were 1.0~100 mg/L nitrogen for each nitrogen compound. The correlation coefficients were more than 0.998. The method can be successfully applied for the determination of each nitrogen compound in different catalytic gasolines.

Key words: catalytic gasolines , distribution, gas chromatography-mass spectrometry （GC-MS）, nitrogen compounds, gas chromatography-nitrogen chemiluminescence detection