高效液相色谱法同时检测化妆品中12种直接染料

doi:10.3724/SP.J.1123.2018.04014

色谱 ›› 2018, Vol. 36 ›› Issue (9): 904-910.DOI: 10.3724/SP.J.1123.2018.04014

高效液相色谱法同时检测化妆品中12种直接染料

潘城, 吴凌, 谢勇, 许文琪, 白洋, 黄永辉, 胡朝阳

福建省产品质量检验研究院, 福建福州 350002

收稿日期:2018-04-12 出版日期:2018-09-08 发布日期:2014-08-05
通讯作者: 潘城,Tel:(0591)83762000,E-mail:pw8877@163.com
基金资助:
福建省产品质量检验研究院院课题项目（KY201526A）.

Simultaneous determination of 12 direct dyes in cosmetics by high performance liquid chromatography

PAN Cheng, WU Ling, XIE Yong, XU Wenqi, BAI Yang, HUANG Yonghui, HU Chaoyang

Fujian Inspection and Research Institute for Product Quality, Fuzhou 350002, China

Received:2018-04-12 Online:2018-09-08 Published:2014-08-05
Supported by:
Subject of Fujian Inspection and Research Institute for Product Quality (No. KY201526A).

摘要/Abstract

摘要：

建立了高效液相色谱分离检测化妆品中12种直接染料的方法。采用XB-C18色谱柱分离，以乙腈-0.02 mol/L乙酸铵水溶液（pH 9.0）为流动相梯度洗脱，二极管阵列检测器检测。结果表明，12种直接染料在线性范围内具有良好的线性关系，相关系数均> 0.999；方法的检出限为0.017~1.7 μ g/g，回收率为85.6%~113.4%，相对标准偏差为1.0%~7.7%；日内和日间精密度分别为0.4%~6.5%和0.2%~7.5%。该法简单快速，灵敏度高，定量准确可靠，适用于化妆品中直接染料的日常检测。

关键词: 高效液相色谱, 化妆品, 直接染料

Abstract:

A method was developed for the simultaneous separation and determination of 12 direct dyes in cosmetics by high performance liquid chromatography (HPLC). The analytes were separated on an XB-C₁₈ column with acetonitrile-0.02 mol/L ammonium acetate aqueous solution (pH 9.0) as the mobile phases, and were detected using a diode array detector. The results indicated that the 12 direct dyes had good linearities with correlation coefficients greater than 0.999. The limits of detection were between 0.017 μ g/g and 1.7 μ g/g. The average recoveries ranged from 85.6% to 113.4%, and the relative standard deviations (RSDs) ranged from 1.0% to 7.7%. The intra-and inter-day RSDs were 0.4%-6.5% and 0.2%-7.5%, respectively. The method is simple, rapid, accurate, and is suitable for the determination of direct dyes in cosmetics.

Key words: cosmetics, direct dyes, high performance liquid chromatography (HPLC)

中图分类号:

O658

潘城, 吴凌, 谢勇, 许文琪, 白洋, 黄永辉, 胡朝阳. 高效液相色谱法同时检测化妆品中12种直接染料[J]. 色谱, 2018, 36(9): 904-910.

PAN Cheng, WU Ling, XIE Yong, XU Wenqi, BAI Yang, HUANG Yonghui, HU Chaoyang. Simultaneous determination of 12 direct dyes in cosmetics by high performance liquid chromatography[J]. Chinese Journal of Chromatography, 2018, 36(9): 904-910.

参考文献

[1] Ren G J, Sun Z J, Wang L Z, et al. Flavour Fragrance Cosmetics, 2017(1):42 任国杰, 孙稚菁, 王灵芝, 等. 香料香精化妆品, 2017(1):42
[2] Robens J F, Dill G S, Ward J M, et al. J Toxicol Appl Pharmacol, 1980, 54(3):431
[3] Zhou X, Tang Y. Dyestuffs and Coloration, 2018, 55(1):11 周鑫, 唐勇. 染料与染色, 2018, 55(1):11
[4] Fathi M R, Asfaram A, Farhangi A. Spectrochim Acta A, 2015, 135:364
[5] Cheng Z J, Zhang L, Guo X, et al. Spectrochim Acta A, 2015, 137:1126
[6] Kallel F, Bouaziz F, Chaari F, et al. Process Saf Environ, 2016, 102:30
[7] Zhang C, Zhang W H, Yu M X, et al. J Porous Mater, 2017, 24(5):1289
[8] Arica T A, Ayas E, Arica M Y, et al. Micropor Mesopor Mat, 2017, 243:164
[9] Fard Z M, Bagheri M, Rabieh S, et al. J Mater Sci-Mater Electron, 2017, 28(13):9618
[10] Salem M A, Bakr E A, Elattar H G. Spectrochim Acta A, 2018, 188:155
[11] Mir A A, Amooey A A, Ghasemi S, et al. J Clean Prod, 2018, 170:570
[12] Walger E, Marlin N, Molton F, et al. Molecules, 2018, 23(2):242
[13] Naseem K, Farooqi Z H, Begum R, et al. J Clean Prod, 2018, 187:296
[14] Deng L, Si Z, Peng X X, et al. Journal of Safety and Environment, 2017, 17(2):677 邓林, 施周, 彭晓旭, 等. 安全与环境学报, 2017, 17(2):677
[15] Ma R H, Zhou G H. Textile Auxiliaries, 2018, 35(3):21 马荣华, 周光红. 印染助剂, 2018, 35(3):21
[16] EC No. 1223/2009
[17] China Food and Drug Administration. Safety and Technical Standards for Cosmetics (2015 Edition). (2015-12-23)[2018-08-15]. http://samr.cfda.gov.cn/directory/web/WS01/images/MjAxNcTqtdoyNji6xbmruOa4vbz+LnBkZg==.pdf 国家食品药品监督管理总局. 化妆品安全技术规范(2015版). (2015-12-23)[2018-08-15]. http://samr.cfda.gov.cn/directory/web/WS01/images/MjAxNcTqtdoyNji6xb mruOa4vbz+LnBkZg==.pdf
[18] Jiang D M, Huang M Y, Fang R M, et al. Chinese Journal of Analysis Laboratory, 2017, 36(3):264 蒋德敏, 黄美英, 方荣美, 等. 分析试验室, 2017, 36(3):264
[19] Fang R Q. Fujian Analysis and Testing, 2017, 26(6):1 方荣谦. 福建分析测试, 2017, 26(6):1
[20] Shi F. Fujian Analysis and Testing, 2010, 19(2):60 侍芳. 福建分析测试, 2010, 19(2):60
[21] Ding Y C, Cao X Z, Wu L N, et al. Chinese Journal of Chromatography, 2008, 26(5):603 丁友超, 曹锡忠, 吴丽娜, 等. 色谱, 2008, 26(5):603
[22] He F P, Shi F, Pan L T. Environmental Pollution and Control, 2011, 33(4):71 贺锋萍, 侍芳, 潘碌亭. 环境污染与防治, 2011, 33(4):71
[23] Lü G, Feng Z J, Cao L J, et al. Physical Testing and Chemical Analysis (Part B:Chemical Analysis), 2011, 47(11):1310 吕刚, 冯智劼, 曹丽静, 等. 理化检验:化学分册, 2011, 47(11):1310
[24] Ling R, Hu W Y, Qiao L. Journal of Instrumental Analysis, 2012, 31(6):730 凌睿, 胡文彦, 乔玲. 分析测试学报, 2012, 31(6):730
[25] Lin H, Xu C X, Yan C R, et al. Chinese Journal of Chromatography, 2013, 31(9):914 林慧, 徐春祥, 颜春荣, 等. 色谱, 2013, 31(9):914
[26] Xiu X L, Luo X, Niu Z Y, et al. Chinese Journal of Chromatography, 2013, 31(10):961 修晓丽, 罗忻, 牛增元, 等. 色谱, 2013, 31(10):961
[27] Gou Y, Geng Z, Zhang Y F, et al. Chinese Journal of Pharmaceutical Analysis, 2017, 37(3):461 苟琰, 耿昭, 张燕飞, 等. 药物分析杂志, 2017, 37(3):461
[28] Lin H, Xu C X, Liu C Z, et al. Journal of Food Safety and Quality, 2017, 8(4):1389 林慧, 徐春祥, 刘成志, 等. 食品安全质量检测学报, 2017, 8(4):1389
[29] Luo L, Dong T, Ma L K. Journal of Chinese Medicinal Materials, 2017, 40(11):2546 罗镭, 董婷, 马临科. 中药材, 2017, 40(11):2546
[30] Li L, Liu J, Wang F. Chinese Journal of Analytical Chemistry, 2016, 44(7):1112 李兰, 刘俊, 王丰. 分析化学, 2016, 44(7):1112
[31] Lü S, Ji H, Pu A J, et al. Dyestuffs and Coloration, 2016, 53(2):54 吕双, 季浩, 蒲爱军, 等. 染料与染色, 2016, 53(2):54
[32] Chen L, Wen J X, Lei Y, et al. Journal of Instrumental Analysis, 2015, 34(9):1008 陈林, 温家欣, 雷毅, 等. 分析测试学报, 2015, 34(9):1008
[33] Dou C Y, Ma Y S, Kang Z S, et al. Journal of Food Safety and Quality, 2015, 6(2):563 窦彩云, 马育松, 康占省, 等. 食品安全质量检测学报, 2015, 6(2):563
[34] Zhong C P, Wei W, Wang Z H, et al. Journal of Food Science, 2014, 35(10):195 钟慈平, 魏炜, 王正虹, 等. 食品科学, 2014, 35(10):195
[35] GB/T 20382-2006

高效液相色谱法同时检测化妆品中12种直接染料

Simultaneous determination of 12 direct dyes in cosmetics by high performance liquid chromatography

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