磁性纳米材料在样品前处理中的应用进展与展望

doi:10.3724/SP.J.1123.2019.07001

摘要/Abstract

摘要：

在样品前处理技术中，吸附剂材料起关键作用。随着纳米材料的发展，越来越多的纳米材料被用作吸附剂以提高对目标物的萃取效率。磁性纳米材料因其具有易于分离、表面可修饰、吸附能力强和良好的生物相容性等优异性能，已广泛应用于分析方法的样品前处理技术中。该文通过对磁性纳米材料在磁性固相萃取和在其他样品前处理技术中的研究与应用展开总结和论述，对磁性纳米材料的稳定性、作用力、比表面积及孔径调控的制备进行了阐述，展望了磁性纳米材料在分离科学中的应用前景，为进一步研究磁性纳米材料的应用提供了参考。

关键词: 磁性纳米材料, 前处理技术, 综述

Abstract:

Adsorbent materials play a key role in sample preparation techniques. With the recent developments in this field, increasing numbers of nanomaterials are being used as adsorbents to improve the extraction efficiency of the target compound. Because of their advantages such as ease of separation, facile surface modification, strong adsorption capacity, and good biocompatibility, magnetic nanomaterials have been widely used for sample preparation techniques in analytical chemistry. In this paper, research trends in magnetic nanomaterials and their application to magnetic solid-phase extraction and other sample pretreatment techniques are summarized and discussed. The stability, force, specific surface area, and pore size control of the magnetic nanomaterials are also described. The application prospects of magnetic nanomaterials in separation science are prospected, which provides a clear outlook and reference for further research into their application.

Key words: magnetic nanomaterials, pretreatment technique, review

丁青青, 张文敏, 张兰. 磁性纳米材料在样品前处理中的应用进展与展望[J]. 色谱, 2020, 38(1): 14-21.

DING Qingqing, ZHANG Wenmin, ZHANG Lan. Advances in magnetic nanomaterials for sample pretreatment and future prospects[J]. Chinese Journal of Chromatography, 2020, 38(1): 14-21.

图/表 3

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Material	Analyte	Method	Technique	Sample	Reference
MSPE: magnetic solid phase extraction; LPME: liquid phase microextraction; GO: graphene oxide; PDA: polydopamine; SPs: superparticles; TpBD: 1, 3, 5-triformylphloroglucinol and benzidine; MIL: materials of institute Lavoisier.
Ferrite nanospheres	domoic acid	MSPE	HPLC-MS/MS	seawater	[19]
Fe₃O₄-N-(n-propyl) ethylenediamine	pesticide multiresidue	QuEChERS	UPLC-MS/MS	kiwifruit	[22]
Fe₃O₄@SiO₂	benzodiazepines	mixed hemimicelle-SPE	HPLC	hair and water	[28]
Fe₃O₄@GO	sulfonamides	MSPE	HPLC-MS/MS	milk	[41]
Magnetic Perhydroxycucurbit [8]uril	cytokinins	MSPE	UPLC-MS/MS	plant	[48]
MIL-53 (Fe)@PDA@Fe₃O₄	sulfonylurea herbicides	MSPE	HPLC	water	[53]
Fe₃O₄SPs@ZIF-8/Zn²⁺	domoic acid	MSPE	HPLC-MS/MS	seafood	[55]
Fe₃O₄@TpBD	bisphenols	-	UV-Vis	aqueous solution	[62]
Water-coated Fe₃O₄	3-monochloropropane-1, 2-diol	LPME	GC-MS	edible oils	[66]

Material	Analyte	Method	Technique	Sample	Reference
MSPE: magnetic solid phase extraction; LPME: liquid phase microextraction; GO: graphene oxide; PDA: polydopamine; SPs: superparticles; TpBD: 1, 3, 5-triformylphloroglucinol and benzidine; MIL: materials of institute Lavoisier.
Ferrite nanospheres	domoic acid	MSPE	HPLC-MS/MS	seawater	[19]
Fe₃O₄-N-(n-propyl) ethylenediamine	pesticide multiresidue	QuEChERS	UPLC-MS/MS	kiwifruit	[22]
Fe₃O₄@SiO₂	benzodiazepines	mixed hemimicelle-SPE	HPLC	hair and water	[28]
Fe₃O₄@GO	sulfonamides	MSPE	HPLC-MS/MS	milk	[41]
Magnetic Perhydroxycucurbit [8]uril	cytokinins	MSPE	UPLC-MS/MS	plant	[48]
MIL-53 (Fe)@PDA@Fe₃O₄	sulfonylurea herbicides	MSPE	HPLC	water	[53]
Fe₃O₄SPs@ZIF-8/Zn²⁺	domoic acid	MSPE	HPLC-MS/MS	seafood	[55]
Fe₃O₄@TpBD	bisphenols	-	UV-Vis	aqueous solution	[62]
Water-coated Fe₃O₄	3-monochloropropane-1, 2-diol	LPME	GC-MS	edible oils	[66]

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