石墨相氮化碳材料在样品前处理中的研究进展

doi:10.3724/SP.J.1123.2019.06032

摘要/Abstract

摘要：

作为一种新型非金属材料，石墨相氮化碳以其独特的优点，如简单的制备方法、优良的化学及热稳定性、良好的生物兼容性和无毒性等，受到越来越多的关注。石墨相氮化碳及其复合材料目前已被广泛应用于电催化、光催化、生物成像等领域。由于具有大的比表面积，同时又是富电子的疏水材料，石墨相氮化碳相关材料被认为是一种理想的样品前处理吸附剂。该文探讨了近年来石墨相氮化碳及其复合材料作为固相萃取、分散固相萃取、磁性固相萃取、固相微萃取吸附剂在样品前处理中的应用，并对未来的发展趋势和应用前景进行了展望，以期为相关领域的研究提供帮助。

关键词: 石墨相氮化碳, 样品前处理, 固相萃取, 分散固相萃取, 磁性固相萃取, 固相微萃取, 吸附剂, 综述

Abstract:

As a new type of non-metallic material, graphite carbon nitride (g-C₃N₄) has attracted increasing attention due to its inherent advantages such as simple preparation, excellent thermal and chemical stability, as well as good biocompatibility and non-toxicity. Nowadays, g-C₃N₄ is widely used in electrocatalysis, photocatalysis, biological imaging, and so on. Because of its large specific surface area, π -electron-rich structure, and hydrophobic properties, g-C₃N₄ is considered an ideal candidate material for sample pretreatment. In this work, g-C₃N₄ and its composites as potential sorbents for solid-phase extraction, dispersive solid-phase extraction, magnetic solid-phase extraction, and solid-phase microextraction are reviewed, and the future trends and prospective are discussed.

Key words: graphitic carbon nitride (g-C₃N₄), sample pretreatment, solid-phase extraction (SPE), dispersive solid-phase extraction (d-SPE), magnetic solid-phase extraction (MSPE), solid-phase microextraction (SPME), sorbent, review

韩丽珍, 杨艺欣, 张婧, 郭敬功, 卢明华. 石墨相氮化碳材料在样品前处理中的研究进展[J]. 色谱, 2020, 38(1): 28-35.

HAN Lizhen, YANG Yixin, ZHANG Jing, GUO Jinggong, LU Minghua. Recent advances in graphitic carbon nitride materials for sample pretreatment[J]. Chinese Journal of Chromatography, 2020, 38(1): 28-35.

图/表 4

图1 g-C3N4的三嗪式和三均三嗪(庚嗪环)式结构图[13]

Fig. 1 Triazine and tri-s-triazine (heptazine) structures of g-C3N4[13]

图2 以MCN为吸附剂的柱辅助分散固相萃取分析磺胺类药物的示意图[47]

Fig. 2 Schematic demonstration of column-assisted dispersive solid-phase extraction (d-SPE) for the analysis of sulfonamides by using MCN as sorbent[47]

图3 合成有序介孔氮化碳及制备介孔氮化碳涂层的固相微萃取纤维示意图[46]

Fig. 3 Schematic demonstration for the synthesis and fabrication of a MCN coated SPME fiber[46] EDA: ethylenediamine; CTC: carbon tetrachloride; MCN: mesoporous carbon nitride.

图4 纳米g-C3N4/CuO材料合成及其作为SPME涂层萃取目标分析物的流程示意图[66]

Fig. 4 Schematic demonstration for the synthesis of nano-g-C3N4/CuO and the usage of it as SPME coating for extraction of target analytes[66] g-C3N4: graphitic carbon nitride; SPME: solid-phase microextraction.

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