Application of metal-organic frameworks and their composites in separation

doi:10.3724/SP.J.1123.2016.08018

Abstract

Abstract:

Metal-organic frameworks (MOFs) are known to be an intriguing class of organic-inorganic hybrid porous solids, synthesized by the assembly of metal ions with organic linkers. MOFs exhibit remarkable properties, such as ultrahigh surface areas, structural diversity, excellent thermal stability, tuneable pore size and the availability of framework functionality, which make MOFs promising for the separation applications. MOFs have shown great potentials as efficient adsorbents and novel stationary phases in adsorption and separation. However, due to the submicron or micron size of most MOFs particles as well as their irregular morphology, the applications of MOFs as stationary phases for sample pretreatment and liquid chromatography were greatly limited. To overcome these obstacles, an effective strategy was applied to fabricate MOF-based composites, combining the excellent separation ability of MOFs with the specific properties of substrates. The substrate materials combining with MOFs included metal nanoparticles, metal oxide nanoparticles, silica, carbonaceous materials, polymers, quantum dots and so on. This review summarizes the current progress in the application of MOFs and their composites for adsorption, sample pretreatment and chromatographic separation. The main contents involve the types and preparation methods of MOF-based composites, the applications of MOFs and their composites in vapor and liquid phase adsorption, solid-phase extraction, solid-phase microextraction, gas chromatographic separation and high performance liquid chromatographic separation. The prospects of MOFs in separation science are also discussed.

Key words: composites, metal-organic frameworks (MOFs), review, separation

CLC Number:

O658

ZHANG Xiaoqiong, WANG Tong, WANG Peiyi, YAO Wei, DING Mingyu. Application of metal-organic frameworks and their composites in separation[J]. Chinese Journal of Chromatography, 2016, 34(12): 1176-1185.

References

[1] Yaghi O M, O'Keeffe M, Ockwig N W, et al. Nature, 2003, 423(6941):705
[2] Kitagawa S, Kitaura R, Noro S. Angew Chem Int Ed, 2004, 43(18):2334
[3] Ferey G. Chem Soc Rev, 2008, 37(1):191
[4] Murray L J, Dinca M, Long J R. Chem Soc Rev, 2009, 38(5):1294
[5] Li J R, Sculley J, Zhou H C. Chem Rev, 2012, 112(2):869
[6] Horcajada P, Gref R, Baati T, et al. Chem Rev, 2012, 112(2):1232
[7] Van de Voorde B, Bueken B, Denayer J, et al. Chem Soc Rev, 2014, 43(16):5766
[8] Yang C X, Yan X P. Chinese Journal of Analytical Chemistry, 2013, 41(9):1297 杨成雄, 严秀平. 分析化学, 2013, 41(9):1297
[9] Furukawa H, Ko N, Go Y B, et al. Science, 2010, 329(5990):424
[10] Eddaoudi M, Kim J, Rosi N, et al. Science, 2002, 295(5554):469
[11] Caskey S R, Wong-Foy A G, Matzger A J. J Am Chem Soc, 2008, 130(33):10870
[12] Zhou W, Wu H, Yildirim T. J Am Chem Soc, 2008, 130(46):15268
[13] Vermoortele F, Ameloot R, Vimont A, et al. Chem Commun, 2011, 47(5):1521
[14] Zlotea C, Phanon D, Mazaj M, et al. Dalton Trans, 2011, 40(18):4879
[15] Gu Z Y, Yan X P. Angew Chem Int Ed, 2010, 49(8):1477
[16] Tanabe K K, Cohen S M. Angew Chem Int Ed, 2009, 48(40):7424
[17] Cohen S M. Chem Rev, 2012, 112(2):970
[18] Hwang Y K, Hong D Y, Chang J S, et al. Angew Chem Int Ed, 2008, 47(22):4144
[19] Fu Y Y, Yan X P. Progress in Chemistry, 2013, 25(2/3):221 付艳艳, 严秀平. 化学进展, 2013, 25(2/3):221
[20] Zhu Q L, Xu Q. Chem Soc Rev, 2014, 43(16):5468
[21] Aijaz A, Akita T, Tsumori N, et al. J Am Chem Soc, 2013, 135(44):16356
[22] Ke F, Zhu J, Qiu L G, et al. Chem Commun, 2013, 49(13):1267
[23] Zhan W, Kuang Q, Zhou J, et al. J Am Chem Soc, 2013, 135(5):1926
[24] Jo C, Lee H J, Oh M. Adv Mater, 2011, 23(15):1716
[25] Fu Y Y, Yang C X, Yan X P. Chem Eur J, 2013, 19(40):13484
[26] Taylor-Pashow K M, Rocca J D, Xie Z, et al. J Am Chem Soc, 2009, 131(40):14261
[27] Qian D, Lei C, Hao G, et al. ACS Appl Mater Interfaces, 2012, 4(11):6125
[28] De Oliveira C A, Da Silva F F, Jimenez G C, et al. Chem Commun, 2013, 48(58):6486
[29] Yang S J, Choi J Y, Chae H K, et al. Chem Mater, 2009, 21(9):1893
[30] Anbia M, Hoseini V. Chem Eng J, 2012, 191:326
[31] Ge L, Wang L, Rudolph V, et al. RSC Adv, 2013, 3(47):25360
[32] Petit C, Bandosz T J. Adv Mater, 2009, 21(46):4753
[33] Petit C, Bandosz T J. Adv Funct Mater, 2010, 20(1):111
[34] Petit C, Bandosz T J. Adv Funct Mater, 2011, 21(11):2108
[35] Petit C, Mendoza B, Bandosz T J. Chemphyschem, 2010, 11(17):3678
[36] Zhou X, Huang W, Shi J, et al. J Mater Chem A, 2014, 2(13):4722
[37] Li L, Liu X L, Geng H Y, et al. J Mater Chem A, 2013, 1(35):10292
[38] Li L, Liu X L, Gao M, et al. J Mater Chem A, 2014, 2(6):1795
[39] Hermannsdörfer J, Friedrich M, Miyajima N, et al. Angew Chem Int Ed, 2012, 51(46):11473
[40] Jiang H L, Lin Q P, Akita T, et al. Chem Eur J, 2011, 17(1):78
[41] Lim D W, Yoon J W, Ryu K Y, et al. Angew Chem Int Ed, 2012, 124(39):9952
[42] Aijaz A, Karkamkar A, Choi Y J, et al. J Am Chem Soc, 2012, 134(34):13926
[43] Sugikawa K, Nagata S, Furukawa Y, et al. Chem Mater, 2013, 25(13):2565
[44] Wang W, Li Y, Zhang R, et al. Catal Commun, 2011, 12(10):875
[45] Lu G, Li S, Guo Z, et al. Nat Chem, 2012, 4(4):310
[46] Liu Q, Low Z X, Li L, et al. J Mater Chem A, 2013, 1(38):11563
[47] Chen X, Ding N, Zang H, et al. J Chromatogr A, 2013, 1304:241
[48] Zhang Y, Lan D, Wang Y, et al. Physica E, 2011, 43(6):1219
[49] Uemura T, Kadowaki Y, Kim C R, et al. Chem Mater, 2011, 23(7):1736
[50] Liu N, Yao Y, Cha J J, et al. Nano Res, 2012, 5(2):109
[51] Seo Y K, Yoon J W, Lee U H, et al. Micropor Mesopor Mater, 2012, 155:75
[52] Zhang X, Han Q, Ding M. RSC Adv, 2015, 5(2):1043
[53] Xing L, Zheng H, Cao Y, et al. Adv Mater, 2012, 24(48):6433
[54] Li Z Q, Wang A, Guo C Y, et al. Dalton Trans, 2013, 42(38):13948
[55] Lu G, Farha O K, Kreno L E, et al. Adv Mater, 2011, 23(38):4449
[56] Schwab M G, Senkovska I, Rose M, et al. Adv Eng Mater, 2008, 10(12):1151
[57] Küsgens P, Zgaverdea A, Fritz H G, et al. J Am Chem Soc, 2010, 93(9):2476
[58] Ramos-Fernandez E V, Garcia-Domingos M, Juan-Alcañiz J, et al. Appl Catal A Gen, 2011, 391(1):261
[59] Yang S, Ye F, Lv Q, et al. J Chromatogr A, 2014, 1360:143
[60] Zhao D, Tan S, Yuan D, et al. Adv Mater, 2011, 23(1):90
[61] Rowe M D, Thamm D H, Kraft S L, et al. Biomacromolecules, 2009, 10(4):983
[62] Imaz I, Hernando J, Ruiz-Molina D, et al. Angew Chem Int Ed, 2009, 48(13):2325
[63] Buso D, Jasieniak J, Lay M D H, et al. Small, 2012, 8(1):80
[64] Jin S, Son H J, Farha O K, et al. J Am Chem Soc, 2013, 135(3):955
[65] Saha S, Das G, Thote J, et al. J Am Chem Soc, 2014, 136(42):14845
[66] Furukawa S, Hirai K, Nakagawa K, et al. Angew Chem Int Ed, 2009, 48(10):17660
[67] Gadzikwa T, Farha O K, Malliakas C D, et al. J Am Chem Soc, 2009, 131(38):13613
[68] Ren J, Musyoka N M, Langmi H W, et al. Int J Hydrogen Energ, 2014, 39(27):14912
[69] Kwon H T, Jeong H K, Lee A S, et al. J Am Chem Soc, 2015, 137(38):12304
[70] Bandosz T J, Petit C. J Colloid Interf Sci, 2009, 338(2):329
[71] Yaghi O M, Li G M, Li H L. Nature, 1995, 378(6558):703
[72] Plabst M, McCusker L B, Bein T. J Am Chem Soc, 2009, 131(50):18112
[73] Zhao X, Bu X, Wu T, et al. Nat Commun, 2013, 4:2344
[74] Liu B, Wu W P, Hou L, et al. Chem Commun, 2014, 50(63):8731
[75] Chen B L, Wang L B, Zapata F, et al. J Am Chem Soc, 2008, 130(21):6718
[76] Maes M, Vermoortele F, Alaerts L, et al. J Am Chem Soc, 2010, 132(43):15277
[77] Seo J S, Whang D, Lee H, et al. Nature, 2000, 404(6781):982
[78] Qi X Y, Li X J, Bai Y, et al. Chinese Journal of Chromato-graphy, 2016, 34(1):10 祁晓月, 李先江, 白玉, 等. 色谱, 2016, 34(1):10
[79] Zhang M, Pu Z Y, Chen X L, et al. Chem Commun, 2013, 49(45):5201
[80] Bonnefoy J, Legrand A, Quadrelli E A, et al. J Am Chem Soc, 2015, 137(29):9409
[81] Hasan Z, Jhung S H. J Hazard Mater, 2015, 283:329
[82] Hou Y, Sun J, Zhang D, et al. Chem Eur J, 2016, 22(18):6345
[83] Khan N A, Jung B K, Hasan Z, et al. J Hazard Mater, 2015, 282:194
[84] Gu Z Y, Chen Y J, Jiang J Q, et al. Chem Commun, 2011, 47(16):4787
[85] Zhao M, Deng C, Zhang X, et al. Proteomics, 2013, 13(23/24):3387
[86] Zheng J, Cheng C, Fang W J, et al. Cryst Eng Comm, 2014, 16(19):3960
[87] Zhang X, Liang Q, Han Q, et al. Analyst, 2016, 141:4219
[88] Liang X T, Liu S Q, Zhu R, et al. J Sep Sci, 2016, 39:2806
[89] Barreto A S, Da Silva R L, Dos Santos Silva S C, et al. J Sep Sci, 2010, 33(23/24):3811
[90] Wang G H, Lei Y Q, Song H C. Anal Methods, 2012, 4(3):647
[91] Ge D, Lee H K. J Chromatogr A, 2012, 1257:19
[92] Rocío-Bautista P, Martínez-Benito C, Pino V, et al. Talanta, 2015, 139:13
[93] Huang Z, Lee H K. J Chromatogr A, 2015, 1401:9
[94] Huo S H, Yan X P. Analyst, 2012, 137(15):3445
[95] Wang Y, Xie J, Wu Y, et al. Microchim Acta, 2014, 181(9/10):949
[96] Cui X Y, Gu Z Y, Jiang D Q, et al. Anal Chem, 2009, 81(23):9771
[97] Yu L Q, Yan X P. Chem Commun, 2013, 49(21):2142
[98] Bagheri H, Javanmardi H, Abbasi A, et al. J Chromatogr A, 2016, 1431:27
[99] Zhang S, Yang Q, Wang W, et al. J Agric Food Chem, 2016, 64(13):2792
[100] Chen B, Liang C, Yang J, et al. Angew Chem Int Ed, 2006, 45(9):1390
[101] Finsy V, Calero S, Garcia-Perez E, et al. Phys Chem Chem Phys, 2009, 11(18):3515
[102] Luebbers M T, Wu T, Shen T, et al. Langmuir, 2010, 26(13):11319
[103] Couck S, Remy T, Baron G V, et al. Phys Chem Chem Phys, 2010, 12(32):9413
[104] Borjigin T, Sun F, Zhang J, et al. Chem Commun, 2012, 48(61):7613
[105] Luebbers M T, Wu T, Shen L, et al. Langmuir, 2010, 26(19):15625
[106] Chang N, Gu Z Y, Yan X P. J Am Chem Soc, 2010, 132(39):13645
[107] Chang N, Yan X P. J Chromatogr A, 2012, 1257:116
[108] Fan L, Yan X P. Talanta, 2012, 99:944
[109] Münch A S, Seidel J, Obst A, et al. Chem Eur J, 2011, 17(39):10958
[110] Yusuf K, Badjah-Hadj-Ahmed A Y, Aqel A, et al. J Chromatogr A, 2015, 1406:299
[111] Yusuf K, Badjah-Hadj-Ahmed A Y, Aqel A, et al. J Chromatogr A, 2016, 1443:233
[112] Yang X, Li C, Qi M, et al. J Chromatogr A, 2016, 1460:173
[113] Alaerts L, Kirschhock C E, Maes M, et al. Angew Chem Int Ed Engl, 2007, 46(23):4293
[114] Alaerts L, Maes M, Giebeler L, et al. J Am Chem Soc, 2008, 130(43):14170
[115] Alaerts L, Maes M, Jacobs P A, et al. Phys Chem Chem Phys, 2008, 10(20):2979
[106] Chang N, Gu Z Y, Yan X P. J Am Chem Soc, 2010, 132(39):13645
[107] Chang N, Yan X P. J Chromatogr A, 2012, 1257:116
[108] Fan L, Yan X P. Talanta, 2012, 99:944
[109] Münch A S, Seidel J, Obst A, et al. Chem Eur J, 2011, 17(39):10958
[110] Yusuf K, Badjah-Hadj-Ahmed A Y, Aqel A, et al. J Chromatogr A, 2015, 1406:299
[111] Yusuf K, Badjah-Hadj-Ahmed A Y, Aqel A, et al. J Chromatogr A, 2016, 1443:233
[112] Yang X, Li C, Qi M, et al. J Chromatogr A, 2016, 1460:173
[113] Alaerts L, Kirschhock C E, Maes M, et al. Angew Chem Int Ed Engl, 2007, 46(23):4293
[114] Alaerts L, Maes M, Giebeler L, et al. J Am Chem Soc, 2008, 130(43):14170
[115] Alaerts L, Maes M, Jacobs P A, et al. Phys Chem Chem Phys, 2008, 10(20):2979
[116] Alaerts L, Maes M, Van der Veen M A, et al. Phys Chem Chem Phys, 2009, 11(16):2903
[117] Yang C X, Yan X P. Anal Chem, 2011, 83(18):7144
[118] Yang C X, Chen Y J, Wang H F, et al. Chem Eur J, 2011, 17(42):11734
[119] Liu S S, Yang C X, Wang S W, et al. Analyst, 2012, 137(4):816
[120] Ameloot R, Liekens A, Alaerts L, et al. Eur J Inorg Chem, 2010, 2010(24):3735
[121] Tanaka K, Muraoka T, Hirayama D, et al. Chem Commun, 2012, 48(68):8577
[122] Ahmed A, Forster M, Clowes R, et al. J Mater Chem A, 2013, 1(10):3276
[123] Fu Y Y, Yang C X, Yan X P. Chem Commun, 2013, 49(64):7162
[124] Xu Y, Xu L, Qi S, et al. Anal Chem, 2013, 85(23):11369
[125] Pan C, Wang W, Chen X. J Chromatogr A, 2016, 1427:125
[126] Li L M, Yang F, Wang H F, et al. J Chromatogr A, 2013, 1316:97
[127] Han S, Wei Y, Valente C, et al. J Am Chem Soc, 2010, 132(46):16358