Advances in magnetic nanomaterials for sample pretreatment and future prospects

doi:10.3724/SP.J.1123.2019.07001

Abstract

Abstract:

Adsorbent materials play a key role in sample preparation techniques. With the recent developments in this field, increasing numbers of nanomaterials are being used as adsorbents to improve the extraction efficiency of the target compound. Because of their advantages such as ease of separation, facile surface modification, strong adsorption capacity, and good biocompatibility, magnetic nanomaterials have been widely used for sample preparation techniques in analytical chemistry. In this paper, research trends in magnetic nanomaterials and their application to magnetic solid-phase extraction and other sample pretreatment techniques are summarized and discussed. The stability, force, specific surface area, and pore size control of the magnetic nanomaterials are also described. The application prospects of magnetic nanomaterials in separation science are prospected, which provides a clear outlook and reference for further research into their application.

Key words: magnetic nanomaterials, pretreatment technique, review

DING Qingqing, ZHANG Wenmin, ZHANG Lan. Advances in magnetic nanomaterials for sample pretreatment and future prospects[J]. Chinese Journal of Chromatography, 2020, 38(1): 14-21.

Figures/Tables 3

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Material	Analyte	Method	Technique	Sample	Reference
MSPE: magnetic solid phase extraction; LPME: liquid phase microextraction; GO: graphene oxide; PDA: polydopamine; SPs: superparticles; TpBD: 1, 3, 5-triformylphloroglucinol and benzidine; MIL: materials of institute Lavoisier.
Ferrite nanospheres	domoic acid	MSPE	HPLC-MS/MS	seawater	[19]
Fe₃O₄-N-(n-propyl) ethylenediamine	pesticide multiresidue	QuEChERS	UPLC-MS/MS	kiwifruit	[22]
Fe₃O₄@SiO₂	benzodiazepines	mixed hemimicelle-SPE	HPLC	hair and water	[28]
Fe₃O₄@GO	sulfonamides	MSPE	HPLC-MS/MS	milk	[41]
Magnetic Perhydroxycucurbit [8]uril	cytokinins	MSPE	UPLC-MS/MS	plant	[48]
MIL-53 (Fe)@PDA@Fe₃O₄	sulfonylurea herbicides	MSPE	HPLC	water	[53]
Fe₃O₄SPs@ZIF-8/Zn²⁺	domoic acid	MSPE	HPLC-MS/MS	seafood	[55]
Fe₃O₄@TpBD	bisphenols	-	UV-Vis	aqueous solution	[62]
Water-coated Fe₃O₄	3-monochloropropane-1, 2-diol	LPME	GC-MS	edible oils	[66]

Material	Analyte	Method	Technique	Sample	Reference
MSPE: magnetic solid phase extraction; LPME: liquid phase microextraction; GO: graphene oxide; PDA: polydopamine; SPs: superparticles; TpBD: 1, 3, 5-triformylphloroglucinol and benzidine; MIL: materials of institute Lavoisier.
Ferrite nanospheres	domoic acid	MSPE	HPLC-MS/MS	seawater	[19]
Fe₃O₄-N-(n-propyl) ethylenediamine	pesticide multiresidue	QuEChERS	UPLC-MS/MS	kiwifruit	[22]
Fe₃O₄@SiO₂	benzodiazepines	mixed hemimicelle-SPE	HPLC	hair and water	[28]
Fe₃O₄@GO	sulfonamides	MSPE	HPLC-MS/MS	milk	[41]
Magnetic Perhydroxycucurbit [8]uril	cytokinins	MSPE	UPLC-MS/MS	plant	[48]
MIL-53 (Fe)@PDA@Fe₃O₄	sulfonylurea herbicides	MSPE	HPLC	water	[53]
Fe₃O₄SPs@ZIF-8/Zn²⁺	domoic acid	MSPE	HPLC-MS/MS	seafood	[55]
Fe₃O₄@TpBD	bisphenols	-	UV-Vis	aqueous solution	[62]
Water-coated Fe₃O₄	3-monochloropropane-1, 2-diol	LPME	GC-MS	edible oils	[66]

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