Recent advances in the application of thin-film microextraction

doi:10.3724/SP.J.1123.2019.05008

Abstract

Abstract:

Thin-film microextraction (TFME), which is a new technique in solid-phase microextraction and correlational research, have gradually attracted the attention of scientists in the field of sample preparation. Because of the high surface area-to-volume ratio and the concurrent increase inthe extraction-phase volume, TFME shows enhanced sensitivity without sacrificing the sampling time, as opposed to other microextraction approaches. Recently, TFME in combination with sample analysis techniques has been widely used for the analysis of forbidden drugs, explosives, pesticides, and veterinary drugs in the pharmaceutical, foodstuff, and environmental industries. This review summarizes the fundamentals, formats, and applications of TFME, as well as its long-term prospects and potential applications.

Key words: thin-filmmicroextraction (TFME), pretreatment, coupling technique, review

GUO Zhiyong, YAO Qiuhong, LIN Qi, CHEN Xi. Recent advances in the application of thin-film microextraction[J]. Chinese Journal of Chromatography, 2020, 38(1): 41-49.

Figures/Tables 2

References

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Sample	Analyte	Instrument	Film material	Reference
VOCs: volatile organic chemicals; DMSO: dimethylsulfoxide; BPA: bisphenol A; IMS: ion mobility spectroscopy; DCBI-MS: desorption of corona beam ion source mass spectrometry; SERS: surface enhanced Raman scattering; PDMS: polydimethyl siloxane; HS: headspace; SWV: square wave voltammetric; PDVB: polydivinyl benzene; PE: polyethylene; MOF: metal organic framework; PAN: polyacrylonitrile; ODS: ostadecyl silane; Nio-66: Nylon-66; PS: polystyrene; NPs: nano particles; CNTs: carbon nano tube; MIPs: molecularly imprinted polymers.
Tomato stem	allelochemical	GC-MS	PDMS	[55]
Peanut leaf	chrysanthemum of methyl ester	GC	PDMS	[56]
Alcohol/garlic metabolite	DMSO, alkyl sulfhydryl	GC-MS	PDMS	[61]
Environmental gas	benzene	GC-MS	PDMS, PDVB	[62]
Urine	aldehydes	HPLC	PE, MOF-199	[58]
Blood	clozapine	HPLC	PAN, ODS	[59]
Fish tissue	acid/alkaline drugs	LC-MS/MS	PS, polydopamine	[62]
Tea	BPA	HPLC-UV	PAN, ODS	[63]
Oil	4-nitrophenol, 2, 4-dinitrophenol	HPLC-UV	cellulose, polydopamine	[64]
Environmental water	BPA, 4-octylphenol, nonylphenol, 4-nonylphenol	HPLC-UV	polyvinyl, fluoride	[71]
Environmental water	BPA	HPLC-UV	Nio-66, ODS	[72, 80]
Cosmetics	retinene, retinol	HPLC	glass electrode, Hg²⁺	[75]
Urine	codeine	IMS	cellulose, aptamer	[57]
Blood/urine	antidepressant drug	DCBI-MS	mesoporous carbon	[60]
Fruit	2, 4-dinitrophenol, organochlorine pesticide	SERS	PAN, Ag NPs	[67]
Environmental water	simetryne	SERS	reagent strips, CNTs	[73]
Chinese herbal medicine	sulfate	HS-SERS	ZnO film, Au NPs	[78]
Wine	SO₂	SERS	ZnO film, Au NPs	[33]
Milk/honey	chloramphenicol	SWV	Pt electrode, MIPs	[64]
VOCs	ethanol, acetone	SWV	ZnO film, TiO₂ NPs	[68]

Sample	Analyte	Instrument	Film material	Reference
VOCs: volatile organic chemicals; DMSO: dimethylsulfoxide; BPA: bisphenol A; IMS: ion mobility spectroscopy; DCBI-MS: desorption of corona beam ion source mass spectrometry; SERS: surface enhanced Raman scattering; PDMS: polydimethyl siloxane; HS: headspace; SWV: square wave voltammetric; PDVB: polydivinyl benzene; PE: polyethylene; MOF: metal organic framework; PAN: polyacrylonitrile; ODS: ostadecyl silane; Nio-66: Nylon-66; PS: polystyrene; NPs: nano particles; CNTs: carbon nano tube; MIPs: molecularly imprinted polymers.
Tomato stem	allelochemical	GC-MS	PDMS	[55]
Peanut leaf	chrysanthemum of methyl ester	GC	PDMS	[56]
Alcohol/garlic metabolite	DMSO, alkyl sulfhydryl	GC-MS	PDMS	[61]
Environmental gas	benzene	GC-MS	PDMS, PDVB	[62]
Urine	aldehydes	HPLC	PE, MOF-199	[58]
Blood	clozapine	HPLC	PAN, ODS	[59]
Fish tissue	acid/alkaline drugs	LC-MS/MS	PS, polydopamine	[62]
Tea	BPA	HPLC-UV	PAN, ODS	[63]
Oil	4-nitrophenol, 2, 4-dinitrophenol	HPLC-UV	cellulose, polydopamine	[64]
Environmental water	BPA, 4-octylphenol, nonylphenol, 4-nonylphenol	HPLC-UV	polyvinyl, fluoride	[71]
Environmental water	BPA	HPLC-UV	Nio-66, ODS	[72, 80]
Cosmetics	retinene, retinol	HPLC	glass electrode, Hg²⁺	[75]
Urine	codeine	IMS	cellulose, aptamer	[57]
Blood/urine	antidepressant drug	DCBI-MS	mesoporous carbon	[60]
Fruit	2, 4-dinitrophenol, organochlorine pesticide	SERS	PAN, Ag NPs	[67]
Environmental water	simetryne	SERS	reagent strips, CNTs	[73]
Chinese herbal medicine	sulfate	HS-SERS	ZnO film, Au NPs	[78]
Wine	SO₂	SERS	ZnO film, Au NPs	[33]
Milk/honey	chloramphenicol	SWV	Pt electrode, MIPs	[64]
VOCs	ethanol, acetone	SWV	ZnO film, TiO₂ NPs	[68]

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