液液提取-固相萃取-高效液相色谱-串联质谱测定人体血液中16种有机磷酸酯

侯敏敏, 史亚利, 蔡亚岐

Determination of 16 organophosphate esters in human blood by high performance liquid chromatography-tandem mass spectrometry combined with liquid-liquid extraction and solid phase extraction

HOU Minmin, SHI Yali, CAI Yaqi

表 1 16种OPEs的英文全称、简称、分子式、相对分子质量及CAS号

Table 1 English name, abbreviation, formula, relative molecular mass, and CAS numbers of the 16 OPEs

Compound Abbreviation Formula Mr CAS No. Trimethyl phosphate TMP C3H9O4P 140.08 512-56-1 Triethyl phosphate TEP C6H15O4P 182.16 78-40-0 Tripropyl phosphate TPrP C9H21O4P 224.23 513-08-06 Tri-n-butyl phosphate TnBP C12H27O4P 266.31 126-73-8 Tri-iso-butyl phosphate TiBP C12H27O4P 266.31 126-71-6 Tris(2-ethylhexyl) phosphate TEHP C24H51O4P 434.63 78-42-2 Tri(2-butoxyethyl) phosphate TBOEP C18H39O7P 398.47 78-51-3 Tri(1-chloro-2-propyl) phosphate TCIPP C9H18Cl3O4P 327.57 13674-84-5 Tri(2-chloroethyl) phosphate TCEP C6H12Cl3O4P 285.49 115-96-8 Tri(1,3-dichloro-2-propyl) phosphate TDCPP C9H15Cl6O4P 430.90 13674-87-8 Tri-phenyl phosphate TPHP C18H15O4P 326.28 115-86-6 Trimethylphenyl phosphate TMPP C21H21O4P 368.36 563-04-2 Cresyl diphenyl phosphate CDPP C19H17O4P 340.31 26444-49-5 2-Ethylhexyl di-phenyl phosphate EHDPP C20H27O4P 362.41 1241-94-7 Resorcinol bis(diphenyl phosphate) RDP C30H24O8P2 574.45 57583-54-7 Bisphenol-A bis(diphenyl phosphate) BABP C39H34O8P2 692.63 5945-33-5