液液提取-固相萃取-高效液相色谱-串联质谱测定人体血液中16种有机磷酸酯

侯敏敏, 史亚利, 蔡亚岐

Determination of 16 organophosphate esters in human blood by high performance liquid chromatography-tandem mass spectrometry combined with liquid-liquid extraction and solid phase extraction

HOU Minmin, SHI Yali, CAI Yaqi

表 2 16种OPEs的质谱参数

Table 2 MS parameters for the 16 OPEs

Analyte	Precursor ion (m/z)	Product ion (m/z)	Declustering potential (DP)/V	Entrance potential (EP)/V	Collision cell exit potential (CXP)/V
TMP	141.1	109.1^*	60	22	10
		79.0	60	29	6
TEP	183.0	99.0^*	54	24	7
		81.0	60	50	8
TPrP	225.4	99.0^*	60	22	7
		141	60	24	10
TnBP	267.4	99.0^*	60	20	10
		155	60	12	10
TiBP	267.4	99.0^*	60	20	10
		155	60	12	10
TEHP	435.3	99.0^*	140	22	9
		113.1	120	16	8
TBOEP	399.3	299.3^*	95	19	10
		199.0	95	21	10
TCIPP	327.0	99.0^*	70	30	10
	329.1	99.0	70	28	10
TCEP	285.0	63.0^*	80	42	10
		99.2	75	30	10
TDCPP	431.1	98.9^*	85	35	9
		208.9	84	20	8
TPHP	327.1	152.0^*	130	42	11
		77.1	130	65	7
TMPP	369.2	166.1^*	147	37	11
		90.9	147	61	8
CDPP	341.1	152.1^*	135	40	10
		165.1	135	40	10
EHDPP	363.2	76.9^*	70	71	7
		251.0	72	12	9
RDP	575.2	419.2^*	190	46	15
		481.1	183	46	15
BABP	693.2	367.0^*	200	45	15
		693.3	200	12	15
TMP-d9	150.1	83.1	90	31	7
TEP-d15	198.1	101.9	65	27	8
TPrP-d21	246.4	102	120	25	9
TCEP-d12	299.1	102	75	30	6
TnBP-d27	294.4	101.9	140	25	10
TPHP-d15	342.3	160	135	47	10
TCIPP-d18	345.1	101.9	75	30	8