液液提取-固相萃取-高效液相色谱-串联质谱测定人体血液中16种有机磷酸酯

侯敏敏, 史亚利, 蔡亚岐

Determination of 16 organophosphate esters in human blood by high performance liquid chromatography-tandem mass spectrometry combined with liquid-liquid extraction and solid phase extraction

HOU Minmin, SHI Yali, CAI Yaqi

表 5 人体血液样本的分析结果

Table 5 Analytical results of human blood samplesng/mL

No. TMP TEP TPrP TnBP TiBP TEHP TBOEP TPHP EHDPP CDPP TMPP BABP RDP TCEP TCIPP TDCPP ∑16OPE 1 - 0.160 - - 0.235 - 0.793 0.462 0.485 - - 0.029 - 2.490 0.290 - 4.94 2 - - - - 0.960 - - 0.332 - - - - - 1.378 0.590 - 3.26 3 - - - - 0.378 0.115 - 0.335 0.165 - - - - 2.415 0.415 - 3.82 4 - - - - - 0.178 - 0.392 0.153 - - - - - 1.615 - 2.34 5 - - - - 0.953 0.290 0.245 0.390 0.230 - - 0.023 - 0.298 0.765 0.460 3.65 6 - - - 0.225 - 0.398 0.185 0.270 0.155 - - - - 0.523 - - 1.76 7 - - - 0.218 0.920 0.138 - - 0.048 - - - 0.132 - 0.240 - 1.69 8 - 0.118 - - 0.365 0.163 0.238 0.252 0.070 - - - - - 0.640 - 1.85 9 - - - 0.673 1.413 - - 0.485 0.123 - - - - - 1.440 - 4.13 10 - 0.263 - 1.173 1.488 0.375 0.713 0.330 0.128 0.795 - - - 0.708 2.015 - 7.99 11 - - - 0.538 0.803 - 1.010 0.910 0.280 - - - - 0.820 2.140 - 6.50 12 - 0.115 - 0.200 0.313 0.878 0.750 0.151 0.210 - - 0.006 - - 0.165 - 2.79 13 - - - 1.505 1.693 0.363 0.410 - 0.325 - - 0.007 - 0.628 2.365 0.538 7.83 14 - - - - 0.270 - 0.153 0.335 - - - 0.005 - - 0.740 - 1.50 15 - - - 0.230 0.813 0.365 0.598 - 0.383 - - - - - 0.415 - 2.80